Category Chemistry

What is the concept of the first british atomic bomb?

Like it or not, science and technology sees unprecedented growth during dire times. This is probably because funding flows into different branches of science like never before, allowing for progress inconceivable during ordinary times. Just like how the COVID-19 pandemic saw a global collective search for vaccines, there have been other times in the past – mostly during wars – when a number of scientific fields received a tremendous boost.

World War II was one such period when scientific progress was at its pinnacle. The ability to split an atom through nuclear fission was discovered in the 1930s. With its ability to release immense power realised, it wasn’t long before the race to build a bomb with it was on. The Manhattan Project was born early in the 1940s and we all know what happened in Japan’s Hiroshima and Nagasaki.

To retain influence                                           

While the Manhattan Project was led by the U.S., it was done in collaboration with the U.K. along with support from Canada. Following the war, however, the U.S. refused to share atomic information with the U.K. With the objective of avoiding complete dependence on the U.S., and to remain a great power and retain its influence, Britain sought to become a nuclear power.

The prospect was discussed in a secret cabinet committee in October 1946. While Chancellor of the Exchequer Hugh Dalton and President of the Board of Trade Stafford Cripps were opposed to the idea of a British bomb citing the huge costs involved, Secretary of State for Foreign Affairs Ernest Bevin had his way and work went ahead. By the time the bomb was ready, however, Winston Churchill’s government came to power.

Penney at the helm

Led by British mathematician William Penney, who had worked on the world’s first atomic bomb in the U.S., the project that went on to become Operation Hurricane began with a secret laboratory tasked with developing the trigger device. With the Soviets managing to successfully explode their first atomic bomb in 1949, Penney’s team was under further pressure. Soon enough, the Brits were ready with their bomb.

Early in 1951, the Australian government agreed that the blast could take place at the uninhabited Monte Bello islands, an archipelago of over 100 islands lying off the coast of north-western Australia. The region was declared a prohibited zone and ships and aircraft were later warned to stay clear of an area of 23,500 nautical square miles off the coast.

Plym carries the bomb

 The troops were mobilised, the first set of vessels left for their destination in January 1952 and six months later HMS Plym, carrying the bomb, and the fleet flagship HMS Campania, made their way. The radioactive core, which used British and Canadian plutonium, was flown out later, and installed in the bomb on Plym very close to the scheduled detonation.

On the morning of October 3, 1952, Britain’s first atomic bomb exploded, sending thousands of tonnes of rock, mud, and sea-water blasting into the air. The Plym was instantly vaporised, with scant bits of red-hot metal from the vessel falling on one of the islands even starting a fire.

An eye-witness account of a Reuters correspondent stationed less than 100 miles away mentions a grand flash followed by the appearance of a grey cloud-a zigzag Z-shaped cloud as opposed to the mushroom cloud that we instantly associate with such detonations.

The success of Operation Hurricane resulted in Penney being knighted. Churchill, who was serving as the Prime Minister of the U.K. for a second time, announced to the House of Commons that there had been no casualties and that everything had gone according to plan. While he did congratulate the Labour Party for their role in the whole project, he also did take a dig at them saying that ‘as an old parliamentarian I was rather astonished that something well over £100 million could be disbursed without Parliament being made aware of it.’

Like it or not, science and technology sees unprecedented growth during dire times. This is probably because funding flows into different branches of science like never before, allowing for progress inconceivable during ordinary times. Just like how the COVID-19 pandemic saw a global collective search for vaccines, there have been other times in the past – mostly during wars – when a number of scientific fields received a tremendous boost.

World War II was one such period when scientific progress was at its pinnacle. The ability to split an atom through nuclear fission was discovered in the 1930s. With its ability to release immense power realised, it wasn’t long before the race to build a bomb with it was on. The Manhattan Project was born early in the 1940s and we all know what happened in Japan’s Hiroshima and Nagasaki.

To retain influence                                           

While the Manhattan Project was led by the U.S., it was done in collaboration with the U.K. along with support from Canada. Following the war, however, the U.S. refused to share atomic information with the U.K. With the objective of avoiding complete dependence on the U.S., and to remain a great power and retain its influence, Britain sought to become a nuclear power.

The prospect was discussed in a secret cabinet committee in October 1946. While Chancellor of the Exchequer Hugh Dalton and President of the Board of Trade Stafford Cripps were opposed to the idea of a British bomb citing the huge costs involved, Secretary of State for Foreign Affairs Ernest Bevin had his way and work went ahead. By the time the bomb was ready, however, Winston Churchill’s government came to power.

Penney at the helm

Led by British mathematician William Penney, who had worked on the world’s first atomic bomb in the U.S., the project that went on to become Operation Hurricane began with a secret laboratory tasked with developing the trigger device. With the Soviets managing to successfully explode their first atomic bomb in 1949, Penney’s team was under further pressure. Soon enough, the Brits were ready with their bomb.

Early in 1951, the Australian government agreed that the blast could take place at the uninhabited Monte Bello islands, an archipelago of over 100 islands lying off the coast of north-western Australia. The region was declared a prohibited zone and ships and aircraft were later warned to stay clear of an area of 23,500 nautical square miles off the coast.

Plym carries the bomb

 The troops were mobilised, the first set of vessels left for their destination in January 1952 and six months later HMS Plym, carrying the bomb, and the fleet flagship HMS Campania, made their way. The radioactive core, which used British and Canadian plutonium, was flown out later, and installed in the bomb on Plym very close to the scheduled detonation.

On the morning of October 3, 1952, Britain’s first atomic bomb exploded, sending thousands of tonnes of rock, mud, and sea-water blasting into the air. The Plym was instantly vaporised, with scant bits of red-hot metal from the vessel falling on one of the islands even starting a fire.

An eye-witness account of a Reuters correspondent stationed less than 100 miles away mentions a grand flash followed by the appearance of a grey cloud-a zigzag Z-shaped cloud as opposed to the mushroom cloud that we instantly associate with such detonations.

The success of Operation Hurricane resulted in Penney being knighted. Churchill, who was serving as the Prime Minister of the U.K. for a second time, announced to the House of Commons that there had been no casualties and that everything had gone according to plan. While he did congratulate the Labour Party for their role in the whole project, he also did take a dig at them saying that ‘as an old parliamentarian I was rather astonished that something well over £100 million could be disbursed without Parliament being made aware of it.’

Picture Credit Google

Who was a famous chemist and physicist who won the Nobel Prize twice?

Pauling, the (near) perfect man for science

On February 28, 1951, American scientist Linus Pauling, along with his co-workers at Caltech, published their theoretical description of the structure of proteins in Proceedings of the National Academy of Sciences. For Pauling, who spent a lifetime in science, it was the perfect way of turning 50. A.S.Ganesh takes a look at the life of Pauling…

There have been only five scientists who have won two Nobel Prizes – Polish-French physicist and chemist Marie Curie (1903, 1911), American scientist Linus Pauling (1954, 1962), American physicist and electrical engineer John Bardeen (1956, 1972), British biochemist Frederick Sanger (1958, 1980), and American stereo chemist Barry Sharpness (2001, 2022). Additionally, there have been two organisations – the International Committee of the Red Cross (1917, 1944, 1963) and the Office of the UN High Commissioner for Refugees (1954, 1981) – that have won multiple Nobel Peace Prizes.

On top of being part of such an elite group, Pauling has done something that makes this feat extra special. For he is the only person ever to receive two unshared Nobel Prizes! In a lifetime spent as a chemist, biochemist, chemical engineer, peace activist, author, and educator, Pauling was awarded the Nobel Prize in Chemistry in 1954 and the Nobel Peace Prize in 1962.

Born in Portland, Oregon, on February 28, 1901, Pauling had science running through him right from the start. For he was the son of a pharmacist, Henry Pauling, and Lucy Pauling, a daughter of a pharmacist.

 

Starts with a chemistry set

It was a friend’s chemistry set that aroused his fascination with chemistry though. As his family lacked the wherewithal to buy him a chemistry set, Pauling instead created his own with chemicals that he found in an iron smelter that had been 54, abandoned. He soon taught himself more in the subject than what he was taught at school.

Despite attending the Washington High School in Portland, he didn’t receive his diploma until 1962 owing to a technicality. This meant that Pauling had received his bachelor’s degree from Oregon State College in 1922, his doctorate in 1925 from the California Institute of Technology and even the Nobel Prize in Chemistry, before he got his diploma!

Gifted Teacher

Having enrolled in college aged 16, he was teaching the course he had taken the year before by age 18. A gifted speaker, it was no wonder therefore when he earned the reputation of being a fabulous teacher after he became a member of the professorial staff of California Institute of Technology in 1927. This was following fellowships after his doctorate that enabled him to study with three renowned physicists – Arnold Sommerfeld in Munich, Ervin Schrodinger in Zurich, and Niels Bohr in Copenhagen.

Pauling remained at Caltech from 1927 until 1964. It was here that he spent most of his time researching and teaching. In addition to being enthusiastic with a willingness to engage in controversial topics, he also had the innate ability to simplify, making even mundane subjects suddenly seem interesting, even to those who knew little about the topic.

 

The alpha helix

On the day he turned 50 on February 28, 1951, Pauling, along with his co-workers at Caltech-American biochemist Robert Corey and the African-American physicist and chemist Herman Branson reported the discovery of the alpha helix. The alpha helix was the first discovery of a helical structure for a protein and they published their theoretical description of the structure of proteins in Proceedings of the National Academy of Sciences.

While Pauling is best known for working out the nature of the chemical bond, his accomplishments were numerous. In addition to determining the structure of proteins, he also discovered the cause of sickle cell anaemia, helped in the creation of synthetic plasma, and even developed an accurate oxygen detector for submarines, among other contributions. It is worth noting that when he won the Nobel Prize in Chemistry, it was not for a single contribution, but for his entire body of work.

The only time since childhood when Pauling’s focus shifted from his work was after World War II, when he took a public stance against the war and the use of nuclear weapons. He was even accused of being pro-Soviet or Communist, but it didn’t deter him from his crusade against nuclear weapons testing. It was his advocacy for nuclear arms control and disarmament that eventually led to him winning the Nobel Peace Prize.

 

Share of controversies

Despite being the poster boy for science, Pauling wasn’t without his share of controversies. Most famous among these was how he championed Vitamin C, as he believed that megadoses could ward off the common cold, going to the extent that it could even prevent or treat cancer. Even though much of his later work was mired in controversy and provoked scepticism, Pauling’s contributions and accomplishments ensure that he is celebrated to this day, nearly 30 years after his death in August 1994.

Picture Credit: Google

Making mendelevium, one atom at a time?

The discovery of mendelevium was announced at the end of April in 1955. It was described by one of its discoverers as “one of the most dramatic in the sequence of syntheses of transuranium elements”.

The search for new elements is something that scientists have been doing for hundreds of years. Once Russian chemist Dmitri Mendeleev organised the elements known at his time according to a repeating, or periodic (and hence the name periodic table), system in the 1860s, the search became a little easier.

This was because the gaps in Mendeleev’s periodic table pointed to elements that weren’t known yet. The properties of these elements, however, could be predicted based on their place in the table and the neighbours around them, thereby making it easier to discover new elements. Mendeleev’s table has since been expanded, to make space for other new elements

One of those new elements discovered was element number 101, named mendelevium after. Mendeleev. American Nobel Prize winner Glenn Seaborg, who was one of the discoverers of the element, wrote that the discovery of mendelevium was “one of the most dramatic in the sequence of syntheses of transuranium elements”, in a chapter co-written by him for The New Chemistry. Additionally, he also wrote in that chapter that “It was the first case in which a new element was produced and identified one atom at a time.”

Begins with a bang                                                                       

Ivy Mike, the first thermonuclear device, was dropped for testing on the Eniwetok Atoll in the Pacific Ocean in 1952, sending a radioactive cloud into the air, from which samples were collected. The lab reports suggested that two new elements-elements 99 (einsteinium) and 100 (fermium) – were discovered from the debris. The discoveries came at a time when there was a race to discover new elements.

 The leading researchers of the U.S. involved in this race were camped at the Radiation Laboratory at the University of California, Berkeley, under the direction of physicist Ernest Lawrence A team of scientists which included Albert Ghiorso, Stanley Thompson, Bernard Harvey, Gregory Choppin, and Seaborg, came up with a plan to produce element 101 using a billion atoms of einsteinium-253 that were formed in a reactor.

The idea was to spread the atoms of einsteinium onto a thin gold foil. As its half-life was about three weeks, the researchers effectively had a week to perform their experiments after receiving it. Based on Ghiorso’s calculations, they were aware that only about one atom of the new element 101 would be produced for every three hours the gold foil was bombarded with alpha particles.

Race against time

As the experiment would yield only a very small amount of the new element, the scientists set up a second gold foil behind the first to catch the atoms. It was a race against time as well as the half-life of element 101 was expected to be a few hours only.

With the Radiation Laboratory atop a hill and the cyclotron at its base, there really was a mad rush to get the samples to the lab on time. The samples “were collected in a test tube, which I took and then jumped in a car driven by Ghiorso”, is how Choppin put it in his own words.

On the night of the discovery, the target was irradiated in three-hour intervals for a total of nine hours. By 4 AM on February 19, 1955, they had recorded five decay events characteristic of element 101 and eight from element 100, fermium. With conclusive evidence of element 101’s existence, Choppin mentions that “We left Seaborg a note on the successful identification of Z =101 and went home to sleep on our success.”

At the end of April 1955, the discovery of element 101 was announced to the world. The university’s press release stated that “The atoms of the new element may have been the rarest units of matter that have existed on earth for nearly 5 billion years… The 17 atoms of the new element all decayed, of course, and the ‘new’ element is for the present extinct once again.”

Cold War era

As element 101 marked the beginning of the second hundred elements of the periodic table, the scientists wanted to name it after Mendeleev, the man behind the periodic table.

Despite the discovery happening during the Cold War era, Seaborg was able to pull enough strings to convince the U.S. government to accept the proposal to name the element after a Russian scientist. The International Union of Pure & Applied Chemistry approved the name mendelevium and the scientists published their discovery in the June 1955 issue of Physical Review Letters.

While only small quantities of mendelevium have ever been produced, more stable isotopes of the element have since been made. The most stable version known as of now has a half-life of over one-and-a-half months, allowing for better opportunities to further study heavy elements and their properties.

Picture Credit : Google

When was mendelevium discovered?

The discovery of mendelevium was announced at the end of April in 1955. It was described by one of its discoverers as “one of the most dramatic in the sequence of syntheses of transuranium elements”.

The search for new elements is something that scientists have been doing for hundreds of years. Once Russian chemist Dmitri Mendeleev organised the elements known at his time according to a repeating, or periodic (and hence the name periodic table), system in the 1860s, the search became a little easier.

This was because the gaps in Mendeleev’s periodic table pointed to elements that weren’t known yet. The properties of these elements, however, could be predicted based on their place in the table and the neighbours around them, thereby making it easier to discover new elements. Mendeleev’s table has since been expanded, to make space for other new elements.

One of those new elements discovered was element number 101, named mendelevium after. Mendeleev. American Nobel Prize winner Glenn Seaborg, who was one of the discoverers of the element, wrote that the discovery of mendelevium was “one of the most dramatic in the sequence of syntheses of transuranium elements”, in a chapter co-written by him for The New Chemistry. Additionally, he also wrote in that chapter that “It was the first case in which a new element was produced and identified one atom at a time.”

Begins with a bang

Ivy Mike, the first thermonuclear device, was dropped for testing on the Eniwetok Atoll in the Pacific Ocean in 1952, sending a radioactive cloud into the air, from which samples were collected. The lab reports suggested that two new elements-elements 99 (einsteinium) and 100 (fermium) – were discovered from the debris. The discoveries came at a time when there was a race to discover new elements. The leading researchers of the U.S. involved in this race were camped at the Radiation Laboratory at the University of California, Berkeley, under the direction of physicist Ernest Lawrence A team of scientists which included Albert Ghiorso, Stanley Thompson, Bernard Harvey, Gregory Choppin, and Seaborg, came up with a plan to produce element 101 using a billion atoms of einsteinium-253 that were formed in a reactor.

The idea was to spread the atoms of einsteinium onto a thin gold foil. As its half-life was about three weeks, the researchers effectively had a week to perform their experiments after receiving it. Based on Ghiorso’s calculations, they were aware that only about one atom of the new element 101 would be produced for every three hours the gold foil was bombarded with alpha particles.

Race against time

As the experiment would yield only a very small amount of the new element, the scientists set up a second gold foil behind the first to catch the atoms. It was a race against time as well as the half-life of element 101 was expected to be a few hours only.

With the Radiation Laboratory atop a hill and the cyclotron at its base, there really was a mad rush to get the samples to the lab on time. The samples “were collected in a test tube, which I took and then jumped in a car driven by Ghiorso”, is how Choppin put it in his own words.

On the night of the discovery, the target was irradiated in three-hour intervals for a total of nine hours. By 4 AM on February 19, 1955, they had recorded five decay events characteristic of element 101 and eight from element 100, fermium. With conclusive evidence of element 101’s existence, Choppin mentions that “We left Seaborg a note on the successful identification of Z =101 and went home to sleep on our success.”

At the end of April 1955, the discovery of element 101 was announced to the world. The university’s press release stated that “The atoms of the new element may have been the rarest units of matter that have existed on earth for nearly 5 billion years… The 17 atoms of the new element all decayed, of course, and the ‘new’ element is for the present extinct once again.”

Cold War era

As element 101 marked the beginning of the second hundred elements of the periodic table, the scientists wanted to name it after Mendeleev, the man behind the periodic table.

Despite the discovery happening during the Cold War era, Seaborg was able to pull enough strings to convince the U.S. government to accept the proposal to name the element after a Russian scientist. The International Union of Pure & Applied Chemistry approved the name mendelevium and the scientists published their discovery in the June 1955 issue of Physical Review Letters.

While only small quantities of mendelevium have ever been produced, more stable isotopes of the element have since been made. The most stable version known as of now has a half-life of over one-and-a-half months, allowing for better opportunities to further study heavy elements and their properties.

Picture Credit : Google 

When does a paper set on fire doesn’t burn to ash? Let’s find out by an experiment!

What you need:

A lighter or a matchbox, a piece of plain paper, water, rubbing alcohol (70% strength), a glass, a measuring cup, a pair of tongs, adult supervision.

What to do:

In the glass, mix 30 ml of water and 90 ml of rubbing alcohol. Stir the mixture well.

Using the tongs, dip the paper into the mixture. Soak it completely.

Lift the paper out of the liquid and shake off any extra droplets. Stow the glass with the mixture away from your experiment table.

Now, using the lighter or a matchstick, set the bottom part of the paper on fire while still holding it with the tongs.

What happens:

If all goes well, the paper should catch fire but it doesn't bum to ash. In fact, the flame goes out, leaving your paper intact.

 Why?

The key is water. If you had dipped the paper into a pure alcohol solution, the paper would have burnt to a crisp.

But when you ignite the paper that is soaked in a water-alcohol mixture, the water absorbs most of the heat generated by the flame and starts to evaporate. This absorption and evaporation of water does not allow the temperature to rise to the point where the paper starts to burn. Needless to say that if the ratio of the alcohol and water is altered, the paper will burn!

Picture Credit : Google 

Can microorganisms blow up balloons?

What you need:

Three small balloons, three packets of yeast, sugar, warm water, three one-litre plastic bottles

What to do:

  • Fill up each bottle with about one inch of very warm water.
  • Put one packet of yeast into each bottle.
  • Now, in the first bottle, put one teaspoon of sugar; in the second one, put two teaspoons, and three teaspoons in the third. Cap all the bottles and shake them well.
  • Open the caps and put the three balloons on the bottles' necks. Leave the bottles undisturbed for a couple of hours.

 What happens:

The balloons begin to inflate in a while. The bottle with the maximum amount of sugar has the most inflated balloon.

 Why?

Yeasts are nothing but a kind of microorganism. They like to feed on sugar. Which is why they are used mostly in baking.

Yeasts require warmth and moisture to become active.

When yeasts begin to feed on sugar, carbon dioxide gas is released. This gas fills the bottle and then inflates the balloon. The more sugar the yeasts get to eat, the more gas they release and the more the balloon inflates.

Picture Credit : Google