The sky has no colour of its own. When sunlight (made up of all colours) passes through the atmosphere it is scattered around by millions of particles in the air. The blue in the sunlight is scattered more than the other colours, so the sky appears to be blue.
When the sun is high overhead, the bulk of its rays intercept the atmosphere at nearly vertical angles. Shorter wavelengths of light, such as violet and blue, are more easily absorbed by air molecules than light from longer wavelengths (that is, from red, orange, and yellow bands in the spectrum). Air molecules then radiate violet and blue light in different directions, saturating the sky. However, the midday sky appears blue, rather than a combination of blue and violet, because our eyes are more sensitive to blue light than to violet light.
When the sun is near the horizon at dawn and dusk, the sun’s rays strike the atmosphere at more-oblique (slanted) angles, and thus these rays must travel a greater distance through the atmosphere than they would at midday. As a result, there are more nitrogen and oxygen molecules and other particles that can block and scatter incoming sunlight. During this long passage, incoming radiation in the shorter blue and violet wavelengths is mostly filtered out, and the influence of these wavelengths over the color of the sky diminishes. What remains are the longer wavelengths, and some of these rays strike dust and other particles near the horizon, as well as the water droplets that make up clouds, to create the red, orange, and yellow tints we enjoy at sunrise and sunset.
Credit : Britannica
Picture Credit : Google