Category The World Around us

Given the right conditions, CFCs can also damage the ozone layer. The CFCs combine with very cool air, producing chlorine — a substance that eats away at ozone. Ozone loss is worst at the area above the South Pole, where a complete “hole” was confirmed in 1985. Reduced ozone levels mean that a greater amount of the Sun’s harmful ultraviolet rays will reach the Earth’s surface, affecting human and animal health, as well as damaging food crops.

The ozone hole is not technically a “hole” where no ozone is present, but is actually a region of exceptionally depleted ozone in the stratosphere over the Antarctic that happens at the beginning of Southern Hemisphere spring (August–October). Satellite instruments provide us with daily images of ozone over the Antarctic region. The ozone hole image below shows the very low values (blue and purple colored area) centered over Antarctica on 4 October 2004. From the historical record we know that total column ozone values of less than 220 Dobson Units were not observed prior to 1979. From an aircraft field mission over Antarctica we also know that a total column ozone level of less than 220 Dobson Units is a result of catalyzed ozone loss from chlorine and bromine compounds. For these reasons, we use 220 Dobson Units as the boundary of the region representing ozone loss. Using the daily snapshots of total column ozone, we can calculate the area on the Earth that is enclosed by a line with values of 220 Dobson Units (the white line in the figure below).

Many people have heard that the ozone hole is caused by chemicals called CFCs, short for chlorofluorocarbons. CFCs escape into the atmosphere from refrigeration and propellant devices and processes. In the lower atmosphere, they are so stable that they persist for years, even decades. This long lifetime allows some of the CFCs to eventually reach the stratosphere. In the stratosphere, ultraviolet light breaks the bond holding chlorine atoms (Cl) to the CFC molecule. A free chlorine atom goes on to participate in a series of chemical reactions that both destroy ozone and return the free chlorine atom to the atmosphere unchanged, where it can destroy more and more ozone molecules. For those who know the story of CFCs and ozone, that is the part of the tale that is probably familiar.

The part of the story that fewer people know is that while the chlorine atoms freed from CFCs do ultimately destroy ozone, the destruction doesn’t happen immediately. Most of the roaming chlorine that gets separated from CFCs actually becomes part of two chemicals that—under-normal atmospheric conditions—are so stable that scientists consider them to be long-term reservoirs for chlorine.

Under normal atmospheric conditions, the two chemicals that store most atmospheric chlorine (hydrochloric acid, and chlorine nitrate) are stable. But in the long months of polar darkness over Antarctica in the winter, atmospheric conditions are unusual. An endlessly circling whirlpool of stratospheric winds called the polar vortex isolates the air in the center. Because it is completely dark, the air in the vortex gets so cold that clouds form, even though the Antarctic air is extremely thin and dry. Chemical reactions take place that could not take place anywhere else in the atmosphere. These unusual reactions can occur only on the surface of polar stratospheric cloud particles, which may be water, ice, or nitric acid, depending on the temperature.

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CFCs (chlorofluorocarbons) are another example of greenhouse gases. They are found in aerosol sprays, refrigeration and air-conditioning systems, and certain types of foam packaging. Awareness of the damage caused by CFCs has meant that some products are labelled as “CFC Free”.

Chlorofluorocarbon (CFC) is an organic compound that contains carbon, chlorine, and fluorine, produced as a volatile derivative of methane and ethane. A common subclass is the hydrochlorofluorocarbons (HCFCs), which contain hydrogen, as well. Freon is DuPont’s brand name for CFCs, HCFCs and related compounds. Other commercial names from around the world are Algofrene, Arcton, Asahiflon, Daiflon, Eskimo, FCC, Flon, Flugene, Forane, Fridohna, Frigen, Frigedohn, Genetron, Isceon, Isotron, Kaiser, Kaltron, Khladon, Ledon, Racon, and Ucon. The most common representative is dichlorodifluoromethane (R-12 or Freon-12).

Chlorofluorocarbons (CFCs) are a family of chemical compounds developed back in the 1930’s as safe, non-toxic, non-flammable alternative to dangerous substances like ammonia for purposes of refrigeration and spray can propellants. Their usage grew enormously over the years. One of the elements that make up CFCs is chlorine. Very little chlorine exists naturally in the atmosphere. But it turns out that CFCs are an excellent way of introducing chlorine into the ozone layer. The ultraviolet radiation at this altitude breaks down CFCs, freeing the chlorine. Under the proper conditions, this chlorine has the potential to destroy large amounts of ozone. This has indeed been observed, especially over Antarctica. As a consequence, levels of genetically harmful ultraviolet radiation have increased.

Work on alternatives for chlorofluorocarbons in refrigerants began in the late 1970s after the first warnings of damage to stratospheric ozone were published. The hydrochlorofluorocarbons (HCFCs) are less stable in the lower atmosphere, enabling them to break down before reaching the ozone layer. Nevertheless, a significant fraction of the HCFCs do break down in the stratosphere and they have contributed to more chlorine buildup there than originally predicted. Later alternatives lacking the chlorine, the hydrofluorocarbons (HFCs) have an even shorter lifetimes in the lower atmosphere. One of these compounds, HFC-134a, is now used in place of CFC-12 in automobile air conditioners. Hydrocarbon refrigerants (a propane/isobutane blend) are also used extensively in mobile air conditioning systems in Australia, the USA and many other countries, as they have excellent thermodynamic properties and perform particularly well in high ambient temperatures. One of the natural refrigerants (along with Ammonia and Carbon Dioxide), hydrocarbons have negligible environmental impacts and are also used worldwide in domestic and commercial refrigeration applications, and are becoming available in new split system air conditioners

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The “greenhouse effect” is a natural process through which gases in the atmosphere trap the Sun’s heat and warm the Earth. Industrial activities such as burning fossil fuels have added to the levels of carbon dioxide and other “greenhouse gases” in the atmosphere. This has increased the greenhouse effect, causing the Earth to get hotter than it would have done naturally.

Glaciers are melting, sea levels are rising, cloud forests are dying, and wildlife is scrambling to keep pace. It has become clear that humans have caused most of the past century’s warming by releasing heat-trapping gases as we power our modern lives. Called greenhouse gases, their levels are higher now than at any time in the last 8000,000 years.

We often call the result global warming, but it is causing a set of changes to the Earth’s climate, or long-term weather patterns, that varies from place to place. While many people think of global warming and climate change as synonyms, scientists use “climate change” when describing the complex shifts now affecting our planet’s weather and climate systems—in part because some areas actually get cooler in the short term.

Climate change encompasses not only rising average temperatures but also extreme weather events, shifting wildlife populations and habitats, rising seas, and a range of other impacts. All of those changes are emerging as human continue to add heat-trapping greenhouses gases to the atmosphere, changing the rhythms of climate that all living things have come to rely on.

What will we do—what can we do—to slow this human-caused warming? How will we cope with the changes we’ve already set into motion? While we struggle to figure it all out, the fate of the Earth as we know it—coasts, forests, farms, and snow-capped mountains—hangs in the balance.

Sunlight shines onto the Earth’s surface, where the energy is absorbed and then radiate back into the atmosphere as heat. In the atmosphere, greenhouse gas molecules trap some of the heat, and the rest escapes into space. The more greenhouse gases concentrate in the atmosphere, the more heat gets locked up in the molecules.

Scientists have known about the greenhouse effect since 1824, when Joseph fourier calculated that the Earth would be much colder if it had no atmosphere. This natural greenhouse effect is what keeps the Earth’s climate livable. Without it, the Earth’s surface would be an average of about 60 degrees Fahrenheit (33 degrees Celsius) cooler.

Levels of greenhouse gases have gone up and down over the Earth’s history, but they had been fairly constant for the past few thousand years. Global average temperatures had also stayed fairly constant over that time—until the past 150 years. Through the burning of fossil fuels and other activities that have emitted large amounts of greenhouse gases, particularly over the past few decades, humans are now enhancing the greenhouse effect and warming Earth significantly, and in ways that promise many effects, scientists warn.

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Ozone is a very important gas in the Earth’s atmosphere. It screens out some of the harmful ultraviolet rays that come from the Sun. The ozone layer is a very fine layer of the gas that surrounds the Earth at a height varying between 15 and 50km (between 9 and 30 miles).

The ozone layer is one layer of the stratosphere, the second layer of the Earth’s atmosphere. The stratosphere is the mass of protective gases clinging to our planet.

The stratosphere gets its name because it is stratified, or layered: as elevation increases, the stratosphere gets warmer. The stratosphere increases in warmth with elevation because ozone gases in the upper layers absorb intense ultraviolet radiation from the sun.

Ozone is only a trace gas in the atmosphere—only about 3 molecules for every 10 million molecules of air. But it does a very important job. Like a sponge, the ozone layer absorbs bits of radiation hitting Earth from the sun. Even though we need some of the sun’s radiation to live, too much of it can damage living things. The ozone layer acts as a shield for life on Earth.

Ozone is good at trapping a type of radiation called ultraviolet radiation, or UV light, which can penetrate organisms’ protective layers, like skin, damaging DNA molecules in plants and animals. There are two major types of UV light: UVB and UVA.

UVB is the cause of skin conditions like sunburns, and cancers like basal cell carcinoma and squamous cell carcinoma. People used to think that UVA light, the radiation used in tanning beds, is harmless because it doesn’t cause burns. However, scientists now know that UVA light is even more harmful than UVB, penetrating more deeply and causing a deadly skin cancer, melanoma, and premature aging. The ozone layer, our Earth’s sunscreen, absorbs about 98 percent of this devastating UV light.

The ozone layer is getting thinner. Chemicals called chlorofluorocarbons (CFCs) are a reason we have a thinning ozone layer. A chlorofluorocarbon (CFC) is a molecule that contains the elements carbon, chlorine, and fluorine. CFCs are everywhere, mostly in refrigerants and plastic products. Businesses and consumers use them because they’re inexpensive, they don’t catch fire easily, and they don’t usually poison living things. But the CFCs start eating away at the ozone layer once they get blown into the stratosphere.

Ozone molecules, which are simply made of three joined oxygen atoms, are always being destroyed and reformed naturally. But CFCs in the air make it very difficult for ozone to reform once it’s broken apart. The ozone layer, which only makes up 0.00006 percent of Earth’s atmosphere, is getting thinner and thinner all the time.

“Ozone holes” are popular names for areas of damage to the ozone layer. This is inaccurate. Ozone layer damage is more like a really thin patch than a hole. The ozone layer is thinnest near the poles.

In the 1970s, people all over the world started realizing that the ozone layer was getting thinner and that this was a bad thing. Many governments and businesses agreed that some chemicals, like aerosol cans, should be outlawed. There are fewer aerosol cans produced today. The ozone layer has slowly recovered as people, businesses, and governments work to control such pollution.

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